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127. Graphite intercalation compounds containing fluorine

โœ Scribed by Nobuatsu Watanabe

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
125 KB
Volume
22
Category
Article
ISSN
0008-6223

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โœฆ Synopsis

The kinetics of intercalation of bromine in graphite were modeled by considering the change in free energy from stage to stage and the diffusion of bromine. The model predicts that Cn,4BrZ is unstable at temperatures above N 250ยฐC. Satisfactory agreement was found between the model and the experimental time-temperature-transformation curves.

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Fluorine-graphite intercalation compounds have been prepared from HOPG and natural graphite powder in the presence of a fluoride such as AgF, WF,, or SbF, at room temperature. The C,F samples obtained were quasi stage 1, 2, and 3 compounds with compositions of Cz ,F-CU hF. The stage 1 hases in the a

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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Ternaryintercalationcompounds,C,F(AlF,),andC,F(MgF,),containingactivefluorineatoms adsorbed on carbon Iavers of host tzraohite were used as a cathode material of lithium cell. The discharge potentials are 2.8-2.5 v at current densities 40400 PA cm-', being higher than that for graphite fluoride belo