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1,2,5-Thiadiazole 1-oxides. 3. An experimental and theoretical investigation of the inversion barrier

✍ Scribed by Amato, Joseph S.; Karady, Sandor; Reamer, Robert A.; Schlegel, H. Bernhard; Springer, James P.; Weinstock, Leonard M.


Book ID
127287784
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
682 KB
Volume
104
Category
Article
ISSN
0002-7863

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3,4-Diphenyl-1,2,5-thiadiazole 1-oxide (1a) in acetonitrile solution is electroreduced to 2,4,6-triphenyl-1,3,5triazine and 3,4-diphenyl-1,2,5-thiadiazole. This behavior is very different from that of similar compounds with other oxidation states of the heterocyclic sulfur atom, such as the 1,1-diox