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1,2,3-Triazolylidenes as Versatile Abnormal Carbene Ligands for Late Transition Metals

✍ Scribed by Neels, Antonia; Albrecht, Martin; Mathew, Paulson


Book ID
115457488
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
272 KB
Volume
130
Category
Article
ISSN
0002-7863

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Preparation of optically pure 1,2,5-trip
✍ Jean-Claude Fiaud; Jean-Yves Legros πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 193 KB

Base-catalyzed isomerization of achiral (E,E)-l ,2,5-triphenylphospholane oxide leads to the racemic (E,Z)isomer. Resolution by Supercritical Fluid Chromatography (SFC) followed by reduction gives the two enantiomers. ## The activity of this new ligand is tested in palladium-catalyzed coupling of c