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1,2,3-Triazole-Incorporated Diacrylate Monomer for Free Radical Cyclopolymerization Through Large Ring Formation

✍ Scribed by Changlin Li; Hewen Liu; Yuesheng Li


Book ID
102940628
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
511 KB
Volume
212
Category
Article
ISSN
1022-1352

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✦ Synopsis


Abstract

A new 1,2,3‐triazole incorporated diacrylate monomer is designed for free radical cyclopolymerization through the formation of 11‐membered rings. NMR analysis on the cyclopolymers including ^1^H, ^13^C, DEPT‐135, and ^1^H–^13^C HMQC spectra support a high degree of cyclization. GPC profiles of the obtained cyclopolymers show unimodal distributions indicative of no chain branching reactions. magnified image