๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

122. Large diameter high strength, high modulus carbon fibers from polyacetylenes

โœ Scribed by C.M Krutchen; D.G Flom; B Gorowitz; B.W Roberts


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
106 KB
Volume
11
Category
Article
ISSN
0008-6223

No coin nor oath required. For personal study only.

โœฆ Synopsis


A carbon ribbon has been produced from a polyimide film whose microstructure can be varied by the degree of restraint or stretch during pyrolysis. The microstructure was varied from a coarse lamellar structure to a welldefined lamellar structure typical of a highly ordered graphite. Increasing the degree of stretch to high values transforms the lamellar to a non-lamellar structure. Subsequent to graphitization, the lamellar structure tensile strength approaches 300,000 psi while its modulus can be as high as 130 x lo6 psi. Transformation to the nonlamellar structure causes a decrease in modulus to approximately 40 X lo6 psi. *This work was supported by the United States Atomic Energy Commission. 128. Development and properties of PAN-based carbon felt-pyrolytic carbon composites* H. 0. Pierson, D. A. Northrop and J. F. Smatana (San&a Laboratories, Albuquerque, New Mexico). The properties of carbon felt-pyrolytic carbon matrix composites based on polyacrylonitrile (PAN) and viscose rayon felt precursors are compared. The PAN-based composite has higher strength, modulus and thermal conductivity, and a significantly reduced thermal expansion. A thermal stress resistance parameter for the PAN-based composite is approximately three times greater.


๐Ÿ“œ SIMILAR VOLUMES


Preparation of high-strength/high-modulu
โœ R. D. Gilbert; Xuechao Hu; R. E. Fornes ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 445 KB ๐Ÿ‘ 2 views

Cellulose triacetate (CTA) fibers were spun from a 35% (w/v) solution of CTA (molecular weight, 95,000) in trifluoroacetic acid (TFA)/CH2CL2 (60/40, v/v) using laboratory-scale spinning equipment, an air gap, and cold MeOH as the coagulant. The resulting fibers, of large diameter (ca. 80 pm) were sa