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122. Intercalation isotherms of AsF5 in various forms of graphite

✍ Scribed by J.G Hooley


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
126 KB
Volume
22
Category
Article
ISSN
0008-6223

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✦ Synopsis


The in-plane superlattice and the twinned domain structure were found by single crystal X-ray diffraction to be preserved after exfoliation and collapse, though the graphite planes were slightly bent. The fractional expansion due to exfoliation was comparable for single crystals and HOPG. The degree of hysteresis was less for single crystals.


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Kinetic and isotherm data for the weight increase of six graphites in AsF, vapor up to 8000 mm at 20Β°C support the production of C\*AsF, and the rapid post-intercalation conversion to C,,AsF, and AsF,. At any time during intercalation, reduction of the pressure to I pm lowers the weight by the calcu

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