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122. Derivatives of 1 : 2 : 3 : 4-tetrahydroxybenzene. Part VII. The synthesis of fumigatin

✍ Scribed by Baker, Wilson ;Raistrick, H.


Book ID
121510616
Publisher
The Royal Society of Chemistry
Year
1941
Weight
262 KB
Category
Article
ISSN
0368-1769

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Fused 1,2-Dithioles. Part VII : Synthesi
✍ Hans-Dietrich Stachel; Barbara Zimmer; Eduard Eckl; Katharina Semmlinger; Wolfga πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 German βš– 268 KB

## Abstract The 1,2‐dithiolosultam derivative 14 was obtained from the (__Ξ±__‐bromoalkylidene)propenesultam derivative 9 (__Schemeβ€…1__). Regioselective cleavage of the two ester groups (β†’1b or 2b) allowed the preparation of derivatives with different substituents at C(3) in the dithiole ring (see 2