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12/10- and 11/13-Mixed Helices in α /γ- and β /γ-Hybrid Peptides Containing C-Linked Carbo- γ -amino Acids with Alternating α - and β -Amino Acids

✍ Scribed by Sharma, Gangavaram V. M.; Jadhav, Vivekanand B.; Ramakrishna, Kallaganti V. S.; Jayaprakash, Pagadala; Narsimulu, Kongari; Subash, Velaparthi; Kunwar, Ajit C.

Book ID: 120323129
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 540 KB
Volume: 128
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja064875a

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Synthesis and conformational studies of a short linear peptide containing a pyrrole amino acid (1, Paa) and a furan amino acid (2, Faa), namely Boc-hGly-Faa-D-Pro-Gly-Paa-hGly-Faa-OMe (3), were carried out in which it was established that peptide 3 adopted a well-defined b-hairpin structure in DMSO-