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1,2-H shift in benzylchlorocarbene: isotope effect and influence of the solvent

โœ Scribed by M.T.H. Liu; R. Bonneau; S. Wierlacher; W. Sander

Book ID
108043643
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
494 KB
Volume
84
Category
Article
ISSN
1010-6030

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## Abstract The ^1^H chemical shifts of 124 compounds containing a variety of functional groups have been recorded in CDCl~3~ and DMSOโ€__d__~6~ (henceforth DMSO) solvents. The ^1^H solvent shift ฮ”ฮด = ฮด(DMSO) โˆ’ ฮด(CDCl~3~) varies from โˆ’0.3 to +4.6 ppm. This solvent shift can be accurately predicted (