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1,2-Epoxycarotinoide 5. Mitteilung, Synthese von (S)-1,2-Epoxy-1,2,7,8,7′,8′-hexahydro-Ψ, Ψ-carotin ((S)-1,2-Epoxy-1,2-dihydro-ζ-carotin)

✍ Scribed by Christoph Arm; Hanspter Pfander

Publisher: John Wiley and Sons
Year: 1984
Tongue: German
Weight: 439 KB
Volume: 67
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19840670619

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✦ Synopsis

Abstract

1,2‐Epoxycarotenoids, Synthesis of (S)‐1,2‐Epoxy‐1,7,8,7′,8′‐hexahydro‐Ψ, Ψ‐carotene ((S)‐1,2‐Epoxy‐1,2‐dihydro‐ζ‐carotene)

The synthesis of (S)‐1,2‐Epoxy‐1,2‐dihydro‐ζ‐carotene ((all‐E,S)‐1) using (E,E)‐farnesol (3) as starting material, and a Sharpless epoxidation as key step is described.

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