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1,2-Diphosphetes with Unusual Structures – A Quantum Chemical Investigation of Bonding Properties☆

✍ Scribed by Wolfgang W. Schoeller; Ulrike Tubbesing; Alexander B. Rozhenko

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
228 KB
Volume
1998
Category
Article
ISSN
1434-1948

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✦ Synopsis

According to quantum chemical calculations at an ab initio diphosphete structures: π donors at phosphorus strongly elongate the P-P bond while electronegative substituents at level parent 1,2-diphosphete is slightly more stable than its corresponding 1,4-diphosphabutadiene structural isomer.

phosphorus increase the interflap angle of the fourmembered ring systems, bringing an envelope conformation The quantum chemical calculations indicate that substituents at phosphorus and to a much less extent at carbon exert to the fore. The lengthening of the P-P bond gives rise to a Möbius-type delocalization within the ring moiety. strong influences on the equilibrium geometries of 1,2-

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