In the title compound, [Fe~2~(C~5~H~5~)~2~(C~6~H~4~F)~2~], the two fluoro and ferrocenyl groups are oriented in a __trans__ arrangement as a result of crystallographic inversion symmetry. The C—F and C—C distances of the ethene framework are 1.365 (3) and 1.331 (5) Å, respectively.
✦ LIBER ✦
1,2-diferrocenyl-1,2-diphenylethane and 1,1-diferrocenyl-1,2-diphenylethane
✍ Scribed by A. N. Nesmeyanov; I. I. Kritskaya
- Book ID
- 112433860
- Publisher
- Springer
- Year
- 1962
- Tongue
- English
- Weight
- 166 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
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In the title compound, [Fe 2 (C 5 H 5 ) 2 (C 26 H 20 N 4 )], two ferrocene units are bridged by a Schiff base linker with an intramolecular FeÁ Á ÁFe separation of 7.42 (2) A ˚.
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The object of this note is to draw attention to the possible importance of concerted molecular reactions, of the type termed 'pericyclic' by Woodward and Hoffmann', in the mechanism of coal liquefaction. This type of pathway has not hitherto been suggested and will be illustrated with reference to