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[1,2-Bis(dimethylphosphino)ethane](cyclopentadienyl)methylzirconium(II) [CpZrMe(DMPE)2]: a catalyst precursor for the selective dimerization of ethylene to 1-butene

✍ Scribed by Wielstra, Ytsen.; Gambarotta, Sandro.; Chiang, Michael Y.

Book ID: 127235009
Publisher: American Chemical Society
Year: 1988
Tongue: English
Weight: 270 KB
Volume: 7
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om00098a027

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Carbon-carbon bond formation versus hydr

Carbon-carbon bond formation versus hydrogen transfer in the reaction of alkynes with mono(cyclopentadienyl)zirconium(II) complexes: regioselective dimerization, cocyclotrimerization, and catalytic cyclotrimerization. The preparation and x-ray structures of Cp(dmpe)XZr[(R)C:C(R')C(R):C(R')] [R = CH3; R' = H, CH3; X = Cl, CH3; dmpe = 1,2-bis(dimethylphosphino)ethane] and of CpZr(dmpe)Cl[C.tplbond.C(t-Bu)][CH:CH(t-Bu)]

✍ Wielstra, Ytsen.; Gambarotta, Sandro.; Meetsma, Auke.; De Boer, Jan L.; Chiang, 📂 Article 📅 1989 🏛 American Chemical Society 🌐 English ⚖ 927 KB