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1,2-Bis[(2R,5R)-2,5-dimethylpyrrolidin-1-yl]benzene

✍ Scribed by Fallon, Gary D. ;Illesinghe, Jayamini ;Campi, Eva M. ;Jackson, W. Roy ;Robinson, Andrea J.

Publisher: International Union of Crystallography
Year: 2003
Tongue: English
Weight: 197 KB
Volume: 59
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s160053680301537x

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, C 18 H 28 N 2 , with a crystallographic twofold rotation axis, can function as a C 2 -symmetric diamine ligand.

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In the title compound, C 11 H 20 N 2 O 3 , the pyrrolidine ring adopts an envelope conformation, where the acetoxy and carbamoyl groups are equatorial. Each molecule interacts, through strong N-HÁ Á ÁO hydrogen bonds, with two adjacent molecules.

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Ethyl (2S*)-2-[(2R*,2′R*,5S*)-2′,5-dimethyl-5′-oxoperhydro-[2,2′]]bifuranyl-5-yl]-2-hydroxyethanoate

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ChemInform Abstract: Application of (2′R

ChemInform Abstract: Application of (2′R,5′R)-2-[(2′,5′-Dimethylpyrrolidin-1-yl)methyl]pyridine and (2′R,5′R)-2-[(2′,5′-Diphenylpyrrolidin-1-yl)methyl]pyridine to the Palladium-Catalyzed Allylic Alkylation.

✍ K. WAERNMARK; R. STRANNE; M. CERNERUD; I. TERRIEN; F. RAHM; K. NORDSTROEM; C. MO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

(2R,4R)-(4-Iodo-5,5-dimethyl-2-hexylsu

(2R,4R)-(4-Iodo-5,5-dimethyl-2-hexylsulfonyl)benzene

✍ Reiß, Guido J. ;Masnyk, Marek 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 252 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê R factor = 0.035 wR factor = 0.066 Data-to-parameter ratio = 15.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

1,2-Bis­[(2R,5R)-2,5-di­methyl­pyrrolidin-1-yl]­benzene

✦ Synopsis

1,2-Bis[(2R,5R)-2,5-dimethylpyrrolidin-1-yl]benzene