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1,2-Bis(2,5-diphenylphospholano)methane, a New Ligand for Asymmetric Hydrogenation.

โœ Scribed by Mark Jackson; Ian C. Lennon


Publisher
John Wiley and Sons
Year
2007
Weight
42 KB
Volume
38
Category
Article
ISSN
0931-7597

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Expanding the Family of Phospholane-Base
โœ Christopher J. Pilkington; Antonio Zanotti-Gerosa ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› John Wiley and Sons โš– 107 KB

Expanding the Family of Phospholane-Based Ligands: 1,2-Bis(2,5-diphenylphospholano)ethane. -The first preparation of the ligand Ph-BPE (I) through an undemanding synthetic pathway is described. It exhibits improved selectivity over other BPE-ligands in the Rh-catalyzed asymmetric hydrogenation. -(