12-Benzoyl-2,3,5,6,9,10,11,12-octahydro-8H-1,4,7,12-benzotrioxaazacyclotetradecine
✍ Scribed by Fallon, Gary D. ;Ventrice, Tina ;Jackson, W. Roy ;Campi, Eva M. ;Patti, Antonio F.
- Publisher
- International Union of Crystallography
- Year
- 2001
- Tongue
- English
- Weight
- 184 KB
- Volume
- 57
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The title compound, C 21 H 25 NO 4 , is the benzoyl derivative of a benzo-aza-crown ether.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.045 wR factor = 0.124 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
2,7 .0 9,11 ]dodeca-2,4,6-trien-1-yl)ethan-1-one
tetraoxa-11-azabenzocyclopentadecene. The ligand has an intramolecular C-HÁ Á ÁO hydrogen bond, resulting in the formation of a six-membered ring. Apart from the near planar OC 6 H 4 O segment, the macrocycle contains gauche C-N and a mixture of gauche and anti C-O and C-C linkages. The nitroso grou