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1,2- and 1,3-O,O-Silyl migration reactions of fluorine-containing monosilylated diols

✍ Scribed by Takashi Yamazaki; Takayuki Oniki; Tomoya Kitazume


Book ID
107857940
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
586 KB
Volume
52
Category
Article
ISSN
0040-4020

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Numerous 3-[(trialkylsilyl)oxymethyl]-furans and -thiophenes undergo a 1.4 O+C silyl migration when treated with n-BuLi/HMPA in THF or DME to produce 2-(trialkylsilyl)-3-(hydroxymethyl)-furans and -thiophenes in good yields.