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1,1,3,3,3-Pentafluoro-2-pentafluorophenyl-1,2-epoxypropane and Trimethylphosphite: Unusual 1,4-Dioxan-2,5-dione Ring Formation.

✍ Scribed by Alexander A. Kadyrov; Dmitrii Silaev; Eli Breuer; Gerd-Volker Roeschenthaler


Publisher
John Wiley and Sons
Year
2003
Weight
105 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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Copolymers of the cyclic ketene acetals, 2-methylene-5,5-dimethyl-1,3-dioxane, 3, (MJ with 2-methylene-l,3-dioxolane, 4, (M2) or 2-methylene-1,3-dioxane, 5, (M2), were synthesized by cationic copolymerization. An experimental method was designed to study the reactivity of these very reactive and ext