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1,1,3,3-Tetraoxo-1,2,3-triazapropene Anion, a New Oxy Anion of Nitrogen: The Dinitramide Anion and Its Salts

โœ Scribed by Bottaro, Jeffrey C.; Penwell, Paul E.; Schmitt, Robert J.


Book ID
125940655
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
263 KB
Volume
119
Category
Article
ISSN
0002-7863

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A Stepwise [4 + 3] Cycloaddition Reactio
โœ Mayr, Herbert ;Heigl, Ulrich W. ;Baran, Janusz ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 435 KB ๐Ÿ‘ 1 views

The 1,3-diphenyl-2-azaallyl anion (1) undergoes [3 + 2 1 cycloaddition reactions with the s-cis-fixed 1,3-dienes 8-11. In contrast, 1,1,2,2,3,3-hexamethyl-4,5-bis(methylene)cyclopenta- ne (7) reacts with 1 to give the [4 + 31 cycloadduct 13 and the linear l,4-addition product 14. This reaction is fo