1,1,1,5,5,5-Hexamethyltrisiloxane: Preparation and some reactions
β Scribed by Dietmar Seyferth; Christian C. Prud'homme; Wei-Liang Wang
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 474 KB
- Volume
- 277
- Category
- Article
- ISSN
- 0022-328X
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## Abstract A nearly zero oxygen balance of organic compounds is characteristic for explosives and high performance solid rocket propellants. Because of its high oxygen content, the introduction of a trinitromethyl group into suitable organic compounds presents an attractive and simple way to produ
cis-disulfoxide 4, or -1,1,5,5\_tetraoxide: disulfone 6 can be accomplished with potassium permanganate and a phase transfer catalyst in a two phase system in 66% yield, with sodium metaperiodate in aqueous methanol in 95% yield, or ruthenium tetraoxide in 70% yield, respectively. Oxidation of the k