1,1'-[Oxybis(methylene)]bis{4-[(hydroxyimino)methyl]pyridinium} dichloride (obidoxime chloride)
✍ Scribed by Van Havere, W. ;Lenstra, A. T. H. ;Geise, H. J. ;Van den Berg, G. R. ;Benschop, H. P.
- Book ID
- 114528538
- Publisher
- International Union of Crystallography
- Year
- 1982
- Weight
- 307 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0567-7408
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## Abstract 1‐[(5‐Amino‐1‐methyl‐1__H__‐1,2,4‐triazol‐4‐ylium)(alkyl/aryl)‐methyl]pyridinium dichlorides 3a–h [geminal bis(heteroarylium) salts] were synthesized in high yield from 5‐amino‐1‐methyl‐1__H__‐1,2,4‐triazole (6a) and the 1‐[(alkyl/aryl)chloromethyl]pyridinium chlorides 1a–h under mild,
The ^14^C labelling of three compounds : HI‐6, TMB‐4 and pyrimidoxime is described from ^14^C‐formic acid, sodium salt. The compounds were prepared by lithiation and formylation with N‐methyl (^14^C)‐formanilide followed by introduction of the hydroxylamine moieties and alkylation of the pyridine. R