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1,1-Diphenyl Ethylene-Mediated Radical Polymerisation: A General Non-Metal-Based Technique For The Synthesis Of Precise Core Cross-Linked Star Polymers

✍ Scribed by Jing Fung Tan; Anton Blencowe; Tor Kit Goh; Greg G. Qiao


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
233 KB
Volume
31
Category
Article
ISSN
1022-1336

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✦ Synopsis


Abstract

This communication details the successful synthesis of low polydispersity core cross‐linked star (CCS) polymers via DPE‐mediated polymerisation. We demonstrate the ability to produce poly(methyl methacrylate) and poly(acrylonitrile) CCS polymers that are currently inaccessible via the two most common non‐metal‐based controlled radical polymerisation techniques (NMP and RAFT polymerisations).

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