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1,1-Dichloro-2,2,2-trihaloethyl Isocyanates and N-(1-Chloro-2,2,2-trihaloethylidene)urethanes in the Synthesis of 4-Trihalomethyl-2H-1,3-benzoxazin-2-ones

✍ Scribed by M.V. Vovk; A.V. Bol'but; P.S. Lebed'; V.I. Boiko


Book ID
111577761
Publisher
Springer US
Year
2004
Tongue
English
Weight
177 KB
Volume
40
Category
Article
ISSN
0009-3122

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Ring Opening of 2-(Benzylamino)-2H-1,4-b
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## Abstract Substituted 2‐(benzylamino)‐2__H__‐1,4‐benzoxazin‐3(4__H__)‐ones are unstable under alkaline and acidic conditions, undergoing opening of the benzoxazinone ring. 2‐Bromo‐2__H__‐1,4‐benzoxazin‐3(4__H__)‐ones show similar degradation under alkaline conditions, while replacement of Br at C