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1,1′-Bis(2-pyridylthio)ferrocene: a new ligand in gold and silver chemistry

✍ Scribed by Barranco, Eva M.; Crespo, Olga; Gimeno, M. Concepción; Jones, Peter G.; Laguna, Antonio; Sarroca, Cristina


Book ID
120828759
Publisher
The Royal Society of Chemistry
Year
2001
Tongue
English
Weight
186 KB
Volume
17
Category
Article
ISSN
1472-7773

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1,1′-Bis(diphenyloxophosphoryl)ferrocene
✍ M.Concepción Gimeno; Peter G Jones; Antonio Laguna; Cristina Sarroca; M.Dolores 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 117 KB

The ligand 1,1%-bis(diphenyloxophosphoryl)ferrocene, dpopf, reacted with silver derivatives to afford mononuclear complexes, [Ag(OClO 3 )(dpopf)] (1), [Ag(dpopf) 2 ]ClO 4 , [Ag(dpopf)(PPh 3 )]ClO 4 , or the dinuclear complex, [{Ag(PPh 3 )} 2 (dpopf)](ClO 4 ) 2 . From 1, other three-, [Ag(dpopf)(SPPh