✦ LIBER ✦
103Rh and 33s hyperfine interactions in tetraphenylarsonium-bis ( maleonitriledithiolato ) rhodate (II), (Ph4As)2[Rh(mnt)2]: a single-crystal EPR-ENDOR study
✍ Scribed by R. Kirmse; K. Köhler; J. Stach; W. Dietzsch; R. Böttcher; L. Golič
- Book ID
- 103024546
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 425 KB
- Volume
- 133
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The complete '03Rh and '% hyperfine coupling tensors of the 4d' low-spin chelate tetraphenylarsoniumbis(maleonitriledithiolato)rhodate(II) doped into the corresponding nickel complex salt have been measured by EPR-ENDOR spectroscopy. Both interactions are small and confirm that the unpaired electron is in an "out-of-plane" x-type molecular orbital. The Rh-S bonds are less covalent than bonds in the isoelectronic Pd(II1) complex.