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10-Ethoxy-3,8-methanoaza[10]annulen, ein 10π-Analogon des Pyridins

✍ Scribed by Hans-Jürgen Gölz; Dr. Joseph M. Muchowski; Dr. Michael L. Maddox


Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
250 KB
Volume
90
Category
Article
ISSN
0044-8249

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3,8-Methanoaza[10]annulen (Homoisochinol
✍ Dr. Werner Tückmantel; Gertraud Andree; Andreas Seidel; Dr. Hans Schmickler; Dr. 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 383 KB
3,8-Methanoaza[10]annulene (Homoisoquino
✍ Dr. Werner Tückmantel; Gertraud Andree; Andreas Seidel; Dr. Hans Schmickler; Dr. 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 399 KB

differs from the latter in that it has a flat chair conformation. The median planes of the two [IOJannulene rings !n 3b are at a slightly different level (difference ca. 0.6 A) which can be explained in terms of the geometry of 6, [14] In the meantime, it has been shown that the syn-isomer 3a (sydan