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1-Methylen-cyclohexadien-(2.5)

✍ Scribed by Plieninger, Hans ;Maier-Borst, Wolfgang

Publisher
Wiley (John Wiley & Sons)
Year
1965
Tongue
English
Weight
248 KB
Volume
98
Category
Article
ISSN
0009-2940

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## Abstract The mechanism of the photolysis of [2.2]paracyclophane‐1,10‐dione (9) was investigated in solution and in argon matrices. The first step of the photolysis involves α‐cleavage of the cyclophane yielding a diradical 11 which could be trapped by ethanol. In argon at 10 K the diradical rapi