The title compound, C 27 H 16 Cl 2 F 6 N 4 O 2 ÁH 2 O, was obtained by the reaction of 2,4-dichlorobenzaldehyde and 2-phenyl-5trifluoromethyl-2H-pyrazol-3-ol in aqueous media without any catalyst. In the crystal structure, both intra-and intermolecular hydrogen bonds are found.
1-Methyl-3-phenyl-5-[3-(trifluoromethyl)phenyl]-4(1H)-pyridinone, a new herbicide
✍ Scribed by Waldrep, Thomas W.; Taylor, Harold M.
- Book ID
- 127394619
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 264 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0021-8561
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📜 SIMILAR VOLUMES
In the title compound, C 24 H 18 F 3 N 3 O, the molecule exists in the enamine-keto tautomeric form. The pyrazolone ring makes dihedral angles of 31.8 (2), 45.4 (2) and 71.2 (2) with the 1-phenyl, aniline and methylene-bound phenyl rings, respectively. An intramolecular N-HÁ Á ÁO hydrogen bond helps
In the title compound, C 21 H 19 ClF 3 N 2 O 6 P, the P atom is in a distorted tetrahedral configuration. In the crystal structure, molecules are linked by intermolecular C-HÁ Á ÁO hydrogen bonds, forming centrosymmetric dimers.
Molecules of the title compound, C 24 H 21 BrN 2 , are linked into chains by a single CÐHÁ Á Á%(arene) hydrogen bond, but CÐ HÁ Á ÁN hydrogen bonds and aromatic %±% stacking interactions are absent.
The NH unit on the exocyclic C C double bond in the title compound, C 25 H 23 N 3 O, interacts with the carbonyl group through an intramolecular hydrogen bond.