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1-Methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione: A novel thiocyanating agent

✍ Scribed by Antonín Klásek; Vladimír Mrkvička

Publisher: Journal of Heterocyclic Chemistry
Year: 2003
Tongue: English
Weight: 57 KB
Volume: 40
Category: Article
ISSN: 0022-152X
DOI: 10.1002/jhet.5570400501

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✦ Synopsis

Abstract

Under mild reaction conditions, the thiocyanato group is selectively transferred from 1‐methyl‐3‐phenyl‐3‐thiocyanato‐1__H__,3__H__‐quinoline‐2,4‐dione (3) to some nucleophiles. Aliphatic primary and secondary amines are converted to S‐cyanothiohydroxylamines, anilines afford p‐thiocyanatoanilines, Wittig reagent is thiocyanated in α‐position, and thiols are oxidized to disulfides.

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