s)-Pinanediol ( I -methoxyvinyl)boronate (1) was prepared from ( I -methoxyvinyl)-lithium and triisopropyl borate followed by (s)-pinanediol. Attempted reaction with (dichloromethy1)lithium failed, and reaction with butylmagnesium chloride followed by acetic acid yielded a mixture of diastereomers o
1-Methoxyvinyl esters
✍ Scribed by H.H. Wasserman; P.S. Wharton
- Book ID
- 103396511
- Publisher
- Elsevier Science
- Year
- 1958
- Tongue
- French
- Weight
- 151 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
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## Abstract Bis‐methoxyvinylcarbonyl‐alkane (10) sind zugänglich über die unbeständigen und tränenreizenden Bis‐chlorvinyl‐ketone (9). Die Umsetzung mit Diaminen führt zu linearen, löslichen Polyamiden vom Typ der vinylenhomologen Polyamide 66. Die Umsetzung von 10 mit Triaminen ergibt vernetzte, u