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1-Heptene hydroformylation over phosphinated silica-anchored rhodium thiolate complexes

✍ Scribed by J.L.G Fierro; M.D Merchán; S Rojas; P Terreros


Book ID
104421263
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
234 KB
Volume
166
Category
Article
ISSN
1381-1169

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Supported rhodium thiolate complexes as
✍ S. Rojas; P. Terreros; J.L.G. Fierro 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 174 KB

The rhodium thiopyrimidine complex [Rh(SPymMe 2 )(CO) 2 ] was tethered to chemically modified SiO 2 substrates and tested as a catalyst in the hydroformylation reaction of 1-heptene. Catalytic performance was monitored under different reaction conditions for several cycles, and compared with the cat