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1 H NMR Study of Hindered Internal Rotation of Tetramethylthiuram Disulfide in Binary Dimethyl Sulfoxide-Chloroform Mixtures

✍ Scribed by Bordbar, Maryam; Bijanzadeh, Hamid Reza; Alizadeh, Naader

Book ID: 125454556
Publisher: Chinese Electronic Periodical Services
Year: 2004
Tongue: English
Weight: 84 KB
Volume: 51
Category: Article
ISSN: 0009-4536
DOI: 10.1002/jccs.200400070

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Bamers to rotation about the partial double C-N' bond were determined from line shape analysis of 'H and I3C dynamic NMR spectra of N',N'-dimethyl-NZ-substituted phenylacetamidines with twelve different substituents on the phenyl ring. The values of AGGc are 51.2-58.7 kJ mol-' and the correlation wi