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1-Ferrocenyl-3-(4-n-octoxylphenyl)propane-1,3-dione

✍ Scribed by Shang, Yadong ;Li, Baoguo ;Hu, Ruijue ;Su, Yongsheng ;Tang, Qun

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 694 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807057005

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✦ Synopsis

The title compound, [Fe(C 5 H 5 )(C 22 H 27 O 3 )], which forms an extended conjugated system and appears in the enol form, is mainly stabilized by an intramolecular hydrogen bond. The Fe-C bond distances are nearly equal with a mean value of 2.0312 A ˚. The two cyclopentadienyl rings are almost parallel to each other, as shown by the dihedral angle of 0.97 (17) . In the structure, ferrocenyl is the more powerful electrondonating group, with the result that the carbonyl group substituted on the benzene ring has the enol form.

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