Single-crystal X-ray study T = 294 K Mean (C-C) = 0.06 A Disorder in solvent or counterion R factor = 0.065 wR factor = 0.219 Data-to-parameter ratio = 12.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
1-Benzyl-3-[4-(dibromomethyl)benzyl]imidazolium hexafluorophosphate
✍ Scribed by Zhang, Huan-Xia ;Qin, Da-Bin ;Jing, Lin-Hai ;Gu, Shao-Jin
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 155 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 153 K Mean (C-C) = 0.004 A Disorder in solvent or counterion R factor = 0.036 wR factor = 0.099 Data-to-parameter ratio = 16.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean (C-C) = 0.005 A R factor = 0.056 wR factor = 0.161 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 27 H 16 Cl 2 F 6 N 4 O 2 ÁH 2 O, was obtained by the reaction of 2,4-dichlorobenzaldehyde and 2-phenyl-5trifluoromethyl-2H-pyrazol-3-ol in aqueous media without any catalyst. In the crystal structure, both intra-and intermolecular hydrogen bonds are found.
In the title compound, [RuCl 2 (C 24 H 26 N 2 )], the multidentate ligand functions as both an arene and a carbene, and occupies four coordination sites. The two Cl atoms complete a distorted octahedron about the Ru atom.