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1-Benzyl-2-[1-(5-methyl-1H-pyrazol-3-yl)-2-phenyl­ethyl]benzimidazole

✍ Scribed by Akkurt, Mehmet ;Pınar, Şerife ;Bouhfid, Rachid ;Moussaif, Ahmed ;Essassi, El-Mokhtar ;Büyükgüngör, Orhan

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
115 KB
Volume
61
Category
Article
ISSN
1600-5368

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In the title compound, C~14~H~13~N~5~O~3~, the dihedral angle formed between the five-membered pyrazole and the benzimidazole ring system is 68.2 (2)°.

Ethyl 1-benzyl-3-phenyl-1H-pyrazole-5-ca
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In the title compound, C 19 H 18 N 2 O 2 , the dihedral angles made by the central pyrazole ring with the benzyl and phenyl rings are 87.00 (9) and 15.23 (9) , respectively. There is a short intermolecular interaction between a C-H bond and the benzyl ring.

3-Methyl-1-phenyl-1H-pyrazol-5-yl 2,4-di
3-Methyl-1-phenyl-1H-pyrazol-5-yl 2,4-dichloro­benzoate
✍ Li, Jiang-Sheng ;Huang, Peng-Mian ;Fan, Mei-Lian ;Duan, Xue-Min ;Zeng, Tao 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 127 KB

In the title compound, C 17 H 12 Cl 2 N 2 O 2 , the dihedral angle formed between the dichlorobenzene and pyrazolyl rings is 38.3 (3) , that between the phenyl and pyrazolyl rings is 46.8 (3) , and that between the two benzene rings is 69.4 (3) .

Ethyl 2-{[(1Z)-(3-methyl-5-oxo-1-phenyl-
Ethyl 2-{[(1Z)-(3-methyl-5-oxo-1-phenyl-1,5-di­hydro­pyrazol-4-yl­idene)(phenyl)­methyl]­amino}-3-phenyl­propanoate
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In the title compound, C 28 H 27 N 3 O 3 , the pyrazolone ring and the N atom of the 2-amino-3-phenylpropanoate group are essentially coplanar. The compound is in an enamine-keto form and its structure is stabilized by one strong intramolecular N-HÁ Á ÁO hydrogen bond.