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1-Benzoyl-3-(4-cyano-5-methyl­sulfanyl-1H-pyrazol-3-yl)thio­urea

✍ Scribed by Wen, Li-Rong ;Li, Ming ;Zhou, Jian-Xia ;Liu, Peng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
297 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, C 13 H 11 N 5 OS 2 , the dihedral angle between the planes of the phenyl and pyrazole rings is 25.62 (2) . The crystal packing is stablized by intra-and intermolecular hydrogen bonds which link the molecules into a three-dimensional network.

📜 SIMILAR VOLUMES

Ethyl 3-methyl-1-(3-methyl­benzoyl)-5-(m
Ethyl 3-methyl-1-(3-methyl­benzoyl)-5-(methyl­sulfanyl)-1H-pyrazole-4-carboxyl­ate
✍ Wen, Li-Rong ;Zhao, Gui-Long ;Li, Ming ;Li, Xue-Mei ;Zhang, Shu-Sheng ;Ouyang, P 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 167 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.043 wR factor = 0.109 Data-to-parameter ratio = 13.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

1-Benzoyl-3-(4-methyl­pyridin-2-yl)thio­
1-Benzoyl-3-(4-methyl­pyridin-2-yl)thio­urea
✍ Yesilkaynak, Tuncay ;Flörke, Ulrich ;Külcü, Nevzat ;Arslan, Hakan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 170 KB
5-Amino-1-(1,5-di­methyl-1H-pyrazol-4-yl
5-Amino-1-(1,5-di­methyl-1H-pyrazol-4-yl­carbonyl)-3-methyl­sulfanyl-1H-1,2,4-triazole
✍ Wen, Li-Rong ;Li, Ming ;Ke, Zi-Qin ;Wang, Xiao 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 133 KB

In the title compound, C 9 H 12 N 6 OS, the pyrazole and triazole rings are nearly coplanar, forming a dihedral angle of 6.50 (9) . There are N-HÁ Á ÁN intermolecular hydrogen-bond interactions in the crystal structure, providing stabilization.

1-Ethyl-5-methyl-3-methyl­sulfanyl-1H-py
1-Ethyl-5-methyl-3-methyl­sulfanyl-1H-pyrazole-4-carboxylic acid
✍ Wen, Li-Rong ;Li, Ming ;Sun, En-Tao ;Zhou, Jian-Xia 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 243 KB

In the crystal structure of the title compound, C 8 H 12 N 2 O 2 S, the molecules are linked into centrosymmetric dimers by a pair of strong O-HÁ Á ÁO hydrogen bonds. Intermolecular SÁ Á ÁS contacts between adjacent dimers generate a sheet-like structure running parallel to the (211) plane.

1-(4-Bromo­phenyl)-3-(4-methyl­benzoyl)t
1-(4-Bromo­phenyl)-3-(4-methyl­benzoyl)thio­urea
✍ Saeed, Aamer ;Flörke, Ulrich 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 151 KB

In the molecule of the title compound, C 15 H 13 BrN 2 OS, the dihedral angle between the two aromatic ring planes is 14.3 (1) . Intermolecular N-HÁ Á ÁBr hydrogen bonds link the molecules into infinite chains along [001].

1-Benzoyl-6-methyl-3-methyl­sulfanyl-6,7
1-Benzoyl-6-methyl-3-methyl­sulfanyl-6,7-dihydro-1H-pyrano[4,3-c]pyrazol-4-one
✍ Hao, Jing-Jun ;Gao, Feng ;Wang, You-Ming ;Li, Zheng-Ming 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 83 KB

The title compound was synthesized by adding benzohydrazide (0.136 g, 1 mmol) to an absolute ethanol solution (30 ml) containing 3-[bis(methylsulfanyl)methylene]dihydro-6-methyl-3H-pyran-2,4-dione (0.232 g, 1 mmol). The mixture was stirred for 5.5 h at room temperature. The product was obtained by s