1-Benzotriazol-1-yl-3,3,3-trifluoro-2-methoxy-2- phenylpropan-1-ones: Mosher-Bt Reagents
β Scribed by Katritzky, Alan R.; Mohapatra, Prabhu P.; Fedoseyenko, Dmytro; Duncton, Matthew; Steel, Peter J.
- Book ID
- 126902360
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 83 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
View of (I), showing 50% probability displacement ellipsoids and the atom-labelling scheme.
In the title compound, C 16 H 15 N 3 O 2 , the dihedral angle between the benzotriazole unit and the other benzene ring is 79.06 (1) . The crystal structure is stabilized by C-HΓ Γ Γ interactions and van der Waals forces.
In the molecule of the title compound, C 21 H 17 N 3 O, the nearly planar benzotriazole ring system is oriented with respect to the planar rings C (benzoyl) and D (terminal phenyl) at dihedral angles of 58.52 (1) and 77.16 (1) , respectively. In the crystal structure, intermolecular C-HΓ Γ ΓN hydrog