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1-Alkenyl- and 1-alkadienylsilatranes in the diels-alder reaction

✍ Scribed by M. G. Voronkov; S. N. Adamovich; V. I. Rakhlin; R. G. Mirskov; M. V. Sigalov


Book ID
112448463
Publisher
Springer
Year
1984
Tongue
English
Weight
220 KB
Volume
33
Category
Article
ISSN
1573-9171

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Dichloropyrazinones are reacted with alkenolates or a Grignard reagent in order to tether a dienophilic side-chain at the 3-position. The compounds smoothly undergo intramolecular Diels-Alder reaction forming tricyclic ring systems. The reactions proceed completely stereoselective yielding only endo