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1-{[5-Fluoro-2-(trifluoro­meth­yl)phenyl]imino­meth­yl}-2-naphthol

✍ Scribed by Zheng, Yun-Fa ;Wang, Liang-Gui ;Yan, Guo-Bing

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
203 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C~18~H~11~F~4~NO, a Schiff base, has been structurally characterized. One intramolecular hydrogen bond influences the conformation of the molecule. The crystal structure is extended into a one-dimensional chain along the c axis via π–π stacking interactions.

📜 SIMILAR VOLUMES

4-{(2,4-Dichloro­phen­yl)[5-hydr­oxy-1-p
4-{(2,4-Dichloro­phen­yl)[5-hydr­oxy-1-phenyl-3-(tri­fluoro­meth­yl)-1H-pyrazol-4­yl]meth­yl}-1-phenyl-3-(trifluoro­meth­yl)-1H-pyrazol-5-ol monohydrate
✍ Yao, Chang-Sheng ;Yu, Chen-Xia ;Tu, Shu-Jiang ;Wang, Xiang-Shan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 214 KB

The title compound, C 27 H 16 Cl 2 F 6 N 4 O 2 ÁH 2 O, was obtained by the reaction of 2,4-dichlorobenzaldehyde and 2-phenyl-5trifluoromethyl-2H-pyrazol-3-ol in aqueous media without any catalyst. In the crystal structure, both intra-and intermolecular hydrogen bonds are found.

2-Meth­oxy-4-(phenyl­imino­meth­yl)pheno
2-Meth­oxy-4-(phenyl­imino­meth­yl)phenol
✍ Lin, Zhi-Dong ;Lin, Zhi-Dong ;Li, Xing ;Huang, Ya-min 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 103 KB
2,2′,5,5′-Tetra­kis(trifluoro­meth­yl)bi
2,2′,5,5′-Tetra­kis(trifluoro­meth­yl)biphen­yl
✍ Dillon, Keith B. ;Zorina, Natalia V. ;Yufit, Dmitry S. ;Howard, Judith A. K. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 384 KB

The title compound, C 16 H 6 F 12 , has been obtained as a byproduct of the reaction between 2,5-bis(trifluoromethyl)phenyllithium and zinc(II) chloride. The asymmetric unit contains two independent molecules with a similar almost perpendicular conformation of the biphenyl fragments.