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1-[5-(4-Chloro­phen­yl)-2-methyl-3-thien­yl]-2-(2,5-dimethyl-3-thien­yl)-3,3,4,4,5,5-hexa­fluoro­cyclo­pent-1-ene: a new photochromic diaryl­ethene compound

✍ Scribed by Pu, Shou-Zhi ;Zheng, Tong ;Xu, Jing-Kun ;Liu, Gang


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
153 KB
Volume
62
Category
Article
ISSN
1600-5368

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Single-crystal X-ray study T = 294 K Mean (C-C) = 0.002 A Disorder in main residue R factor = 0.039 wR factor = 0.105 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The title compound, C~17~H~12~F~6~OS~2~, is a new nonsymmetric photochromic diarylethene which contains 3-thienyl substituents. The distance between the two reactive C atoms in the molecule is 3.550 (7) Å. The dihedral angles between the central cyclopentene ring and two thiophene rings are 44.7 (3)

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The title compound, C~27~H~14~F~10~S~2~, is a new symmetrical photochromic diarylethene derivative which can be used potentially for optical recording media and other optoelectronic device materials. The distance between the two reactive C atoms is 3.571 (4) Å. The dihedral angles between the thioph

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The title compound, C~27~H~14~F~10~S~2~, is a new symmetrical photochromic diarylethene derivative which can be used potentially for optical recording media and other optoelectronic device materials. There are two independent molecules in the asymmetric unit. Both adopt a photoactive antiparallel co