In the title compound, C 15 H 11 BrO, the dihedral angle between the two benzene rings is 49.93 (8) . The molecules are arranged into infinite chains along the c axis through weak C-Hร ร รBr interactions. The chains are stacked along the a axis, forming layers.
1-(4-Methoxyphenyl)-3,3-bis(methylsulfanyl)-2-phenylprop-2-en-1-one
โ Scribed by Palani, K. ;Ponnuswamy, M. N. ;Jaisankar, P. ;Srinivasan, P. C.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 120 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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โฆ Synopsis
In the title compound, C 18 H 18 O 2 S 2 , there are two independent and conformationally similar molecules in the asymmetric unit. In one of the molecules, the dihedral angle between the two aromatic rings is 77.1 (2) , and in the other it is 78.2 (2) . The two independent molecules are linked by a C-Hร ร ร interaction.
๐ SIMILAR VOLUMES
In the title molecule, C 15 H 12 O 2 , the carbonyl group is in an s-cis conformation. The dihedral angle between the planes of the 4-hydroxyphenyl group and the phenyl ring is 34.96 (10) . Electron conjugation is observed between the central รCH CHรC( O)ร group and the attached rings. The crystal s
The title compound, C 16 H 13 BrO 2 , crystallizes with two independent molecules (A and B) in the asymmetric unit. The dihedral angle between the two benzene rings is 45.94 ( 8) in molecule A and 46.82 ( 7) in molecule B. The crystal packing is stabilized by weak C-Hร ร ร interactions.
In the title compound, C 18 H 18 O 4 , the molecule is slightly twisted with a dihedral angle of 17.49 (5) between the two benzene rings. All of the methoxy substituents lie almost in the planes of the benzene rings to which they are attached. The crystal structure is stabilized by intermolecular C-
In the title compound, C 22 H 17 NO, the dihedral angles between the central benzene ring and the two terminal phenyl rings are 48.20 (4) and 49.62 (4) , resulting in a substantially twisted molecular conformation. Weak C-Hร ร ร interactions help to consolidate the centrosymmetric crystal packing.