1-(2-Pyridyl)-5-methylimidazole
✍ Scribed by Mente, D. C. ;Sundberg, R. J. ;Bryan, R. F.
- Book ID
- 114524725
- Publisher
- International Union of Crystallography
- Year
- 1977
- Weight
- 383 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0567-7408
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📜 SIMILAR VOLUMES
C5 to C2 position migratiw of 2-trialkylsilyl and thiophctgd groups have bus observed upon lithhth at the Cs-position of cxxqwkg C2-subwituted l-muhylixnkko~. Double brominelithium exchange of I-mcthyL2$sle (5) affords a facile, qluwthive and uuequivocal synthc& of 2,5\_dilithio\_l~l-~~ (4). Raction
The title compound, C 13 H 10 N 4 , is a non-linear 2,4-bipyridyltype ligand. Adjacent centrosymmetric molecules are linked together by pairs of intermolecular NÐHÁ Á ÁN hydrogen bonds. The dimers stack along the b axis.
## Abstract The ionic liquid 1‐butyl‐3‐methylimidazolium hexafluorophosphate, (BMI^+^)(PF~6~^−^), has been used as a solvent in the sonochemical reaction of 1‐methylimidazole and [Fe(CO)~5~] at 40−50 °C under air. The reaction afforded [(1‐methylimidazole)~6~Fe^II^](PF~6~)~2~, the structure of whic