1-[(2-Chloro-3,4-dimethoxybenzylidene)amino]adamantane
✍ Scribed by Işık, Şamil ;Köysal, Yavuz ;Septiog~lu, Ebubekir ;Çalış, Ünsal
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 122 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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## The Crystal and Molecular Structure of 2-[(3,4-dimethoxybenzylidene)amino]adamantane The crystal structure of the title compound, C 19 H 25 NO 2 was determined by single crystal X-ray diffraction technique. The crystal data are Orthorombic, space group Pbca, with a = 9.2119( ), b = 9.5555(4), c
The title compound, C 16 H 12 BrClN 4 O, contains two benzene rings and a triazole ring which is substituted at the 1,2,4positions. The crystal structure of (I) is stabilized by NÐ HÁ Á ÁO and %±% stacking interactions.
The title molecule, C 16 H 12 ClFN 4 O, contains three planar rings. The molecules are linked by an intermolecular hydrogen bond. The p-chlorophenyl and p-¯uorophenyl rings form dihedral angles of 61.2 (4) and 12.38 (10) , respectively, with the triazole ring.
In the title compound, C 12 H 8 ClN 3 O 2 , the dihedral angle between the least-squares planes of the pyridine and benzene rings is 20.8 (1) . In the crystal structure, molecules pack nearly parallel along the a axis, with some stacking interactions.