1-(2-Bromophenyl)cyclohexanecarbonitrile
✍ Scribed by Lemmerer, Andreas ;Michael, Joseph P.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 161 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The cyclohexane ring in the title compound, C 13 H 14 BrN, adopts a chair conformation with an axial nitrile substituent. Ar-HÁ Á ÁN bridges stabilize the crystal packing.
📜 SIMILAR VOLUMES
The title compound, C 10 H 9 BrO, was produced via the [2 + 2]cycloaddition reaction of 4-bromostyrene with trichloroacetyl chloride followed by dechlorination. The molecule is folded, as shown by the dihedral angle of 45.5 (7) between the rings.
Molecules of the title compound, C 30 H 22 Br 2 O 2 , lie across crystallographic inversion centres. The dihedral angle between the phenyl and bromobenzene rings is 23.88 (8) . Weak C-HÁ Á ÁO interactions link the molecules into ribbons along the a axis.
In the molecule of the title compound, C 18 H 21 F 2 N 3 , the 1,3,5triazacyclohexane ring has a chair conformation. Intramolecular C-HÁ Á ÁF and C-HÁ Á ÁN hydrogen bonds may be effective in the stabilization of the structure.