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1-(1H-Benzimidazol-2-yl)-3-(3-chlorophenyl)prop-2-en-1-one

✍ Scribed by Adohi-Krou, A. ;Ouattara, M. ;Zoro-Diama, E. G. ;Akonan, L. ;Aycard, J. P.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
421 KB
Volume
63
Category
Article
ISSN
1600-5368

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The title compound, C 15 H 11 ClO 2 , is almost planar and adopts an E configuration. The dihedral angle between the two benzene rings is 10.76 ( 6) . An intramolecular O-HÁ Á ÁO hydrogen bond generates an S(6) ring motif. Molecules are arranged in layers approximately parallel to the (204) plane an

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The enone fragment, the thiophene ring and the benzene ring of the title molecule, C 13 H 9 ClOS, are all essentially individually planar. The thiophene ring is disordered over two sites, corresponding to a rotation of approximately 180 about the single C-C bond to which it is attached. The crystal

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The title compound, C~21~H~15~ClO, was prepared from biphenyl-4-carbaldehyde and 4-chloroacetophenone. Single crystals were obtained from acetone. The compound is isostructural with the corresponding Br compound. The molecule deviates significantly from planarity.